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Excluded volume effect in polyacrylonitrile solutions
Authors:Silvia Ioan  Gabriela Grigorescu  Cătălina Ioan  Bogdan C. Simionescu
Affiliation:(1) "ldquo"P. Poni"rdquo" Institute of Macromolecular Chemistry, RO-6600 Jassay, Romania;(2) Department of Macromolecules, "ldquo"Ghe. Asachi"rdquo" Technical University, RO-6600 Jassy, Romania
Abstract:Summary The paper discusses the validity criteria of the theories on the excluded volume effect for high molecular weight PSgr(Z) polyacrylonitrile. The experimental data obtained for both the interpenetration function psgr(Z) and the hydrodynamic function II(Z) satisfactorily approach the theoretical predictions of the renormalized two-parameter theory for high excluded volume.
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