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Experimental investigation and thermodynamic modeling of the Mg-Si-Zn system
Authors:Man WangPeisheng Wang  Shuhong Liu  Yong Du  Honghui Xu  Wenqing Zhang
Affiliation:
  • a State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, PR China
  • b Science Center for Phase Diagram & Materials Design and Manufacture, Central South University, Changsha, Hunan 410083, PR China
  • c State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, PR China
  • Abstract:
    The isothermal section at 327 °C for the Mg-Si-Zn system has been determined by means of X-ray diffraction (XRD) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX). No ternary compound has been observed in this work. Five three-phase regions, (Zn)+(Si)+Mg2Zn11, Mg2Zn11+MgZn2+Mg2Si, Mg2Zn3+MgZn2+Mg2Si, Mg51Zn20+MgZn+Mg2Si, and Mg51Zn20+Mg2Si+(Mg), have been determined. No appreciable ternary solubility has been detected. An optimal set of thermodynamic parameters for the Mg-Si-Zn system has been obtained by considering the experimental data from both the present work and the literature. The agreement between calculation and experiment is reasonable.
    Keywords:Mg-Si-Zn system   Isothermal section   Thermodynamic modeling   XRD   SEM/EDX
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