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The physicochemical characteristics of modified carbon fibers by Fluorination
Authors:Young-Seak?LeeEmail author  Byoung-Ky?Lee  Jae-Seong?Rho
Affiliation:(1) Department of Chemical Engineering & Nanotechnology Center, Sunchon National University, 540-742 Sunchon, Korea;(2) Advanced Research Center, Chungnam National University, 305-764 Daejeon, Korea;(3) Department of Fine Chemical Engineering and Chemistry, Chungnam National University, 305-764 Daejeon, Korea
Abstract:The surface of PAN-based carbon fiber was directly modified with fluorine-oxygen mixtures at room temperature. The surface characteristics of the modified fiber were determined by using X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and dynamic contact angle analyzer. The surface free energy was also calculated with the Owens-Wendt geometric mean method using water and methylene iodide contact angle. The surface of carbon fiber was changed into hydrophilicity by the formation of semicovalent C-F bond and C-O bond depending on reaction conditions and the surface free energy of oxyfluorinated fiber was significantly increased.
Keywords:Carbon Fiber  Fluorination  X-ray Photoelectron Spectroscopy (XPS)  Surface Modification
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