Thermodynamic modeling of vapor-liquid equilibria and excess properties of the binary systems containing diethers and n-alkanes by cubic equation of state |
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Authors: | Slobodan?P??erbanovi? Ivona?R?Grguri? Mirjana?Lj?Kijev?anin Aleksandar?Z?Tasi? Email author" target="_blank">Bojan?D?Djordjevi?Email author |
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Affiliation: | (1) Department of Chemical Engineering, Faculty of Technology and Metallurgy, University of Belgrade, 11120 Belgrade, Karnegijeva 4, Serbia and Montenegro |
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Abstract: | A comparison of the performances of two different approaches of cubic equations of state models, based on a classical van
der Waals and mixing rules incorporating theG
E
equation, was carried out for correlation of Vapor-Liquid Equilibria (VLE), HE and C
P
E
data alone, and simultaneous correlation of VLE+HE, VLE+C
P
E
, HE +C
P
E
and VLE+HE +C
P
E
data for the diethers (1,4-dioxane or 1,3-dioxolane) with n-alkane systems. For all calculations the Peng-Robinson-Stryjek-Vera
cubic equation of state (PRSV CEOS) was used. A family of mixing rules for the PRSV CEOS based on the Modified van der Waals
one-fluid mixing rule (MvdW1) and two well-known CEOS/GE mixing rules (MHV1 and MHV2), was considered. The NRTL equation, as the GE model with linear or reciprocal temperature dependent parameters, was incorporated in the CEOS/GE models. The results obtained by the CEOS/GE models exhibit significant improvement in comparison to the MvdW1 models. |
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Keywords: | Cubic Equation of State Thermodynamic Properties Diether n-Alkane Simultaneous Correlation |
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