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利用地沟油和对苯二甲酸废料生产醇酸树脂的理论和实践
引用本文:梁建新,徐家燕,梁善成,谢尚业,李崇铭,王维熙,袁爱群.利用地沟油和对苯二甲酸废料生产醇酸树脂的理论和实践[J].中国涂料,2013(4):72-76.
作者姓名:梁建新  徐家燕  梁善成  谢尚业  李崇铭  王维熙  袁爱群
作者单位:广西柳州鱼峰制漆股份有限公司;广西科技大学生物与化学工程学院;广西民族大学化学化工学院化学与生物转化过程新技术重点实验室
基金项目:广西科学研究与技术开发计划项目(桂科攻11107013-6)
摘    要:以地沟油和对苯二甲酸废料为原料合成醇酸树脂,通过对原料的组成及合成工艺的理论分析,确定采用碱漂法去除地沟油的杂质,采用混合酸多步法除去对苯二甲酸废料中的杂质,采用二段法合成醇酸树脂。经中试和扩大生产,合成的醇酸树脂固形物中40%来自地沟油,25%来自对苯二甲酸废料,其余为甘油和松香,与传统工艺相比,本工艺生产醇酸树脂每吨原料成本降低1 522元,是一条经济有效的资源化利用工艺路线。

关 键 词:地沟油  对苯二甲酸废料  醇酸树脂

Theory and Practice of Production of Alkyd Resin from Waste Cooking Oil and Waste Terephthalic Acid
LIANG Jian-xin,XU Jia-yan,LIANG Shan-cheng,XIE Shang-ye,LI Chong-ming,WANG Wei-xi,YUAN Ai-qun.Theory and Practice of Production of Alkyd Resin from Waste Cooking Oil and Waste Terephthalic Acid[J].China Paint,2013(4):72-76.
Authors:LIANG Jian-xin  XU Jia-yan  LIANG Shan-cheng  XIE Shang-ye  LI Chong-ming  WANG Wei-xi  YUAN Ai-qun
Affiliation:1.Guangxi Liuzhou Yufeng paint Co.,Ltd.,Liuzhou 545005,Guangxi,China;2.College of Biological and Chemical Engineering,Guangxi University of Science and Technology,Liuzhou 545006,Guangxi,China;3.College of Chemistry and Chemical Engineering,Guangxi University for Nationalities,Key Laboratory of New Technology of Chemical and Biological Transformation Processes,Nanning 530006,Guangxi,China)
Abstract:Alkyd resin was prepared by waste cooking oil and waste terephthalic acid.Based on the theoretical analysis of composition of raw materials and synthesis process,alkyd resin was developed by second section synthesis method after removing impurities from waste cooking oil by the alkali bleaching method and removing the impurities from waste terephthalic acid by mixed acid multi-step method.Through the pilot and expand production,the synthesized alkyd resin solid is tested to be composed by 40% waste cooking oil,25% waste terephthalic acid,and others including glycerin and rosin.Compared with the traditional process,this process can reduce raw material cost by 1 522 RMB per ton,which is an economic process of resource recycling.
Keywords:waste cooking oil  waste terephthalic acid  alkyd resin
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