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Improved hydrogen storage properties of MgH2 with Ni-based compounds
Authors:Qiuyu Zhang  Lei Zang  Yike Huang  Panyu Gao  Lifang Jiao  Huatang Yuan  Yijing Wang
Affiliation:1. Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China;2. Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China;3. School of Material Science and Engineering, Hebei University of Technology, Tianjin 300071, China
Abstract:The nanoscaled Ni-based compounds (Ni3C, Ni3N, NiO and Ni2P) are synthesized by chemical methods. The MgH2-X (X = Ni3C, Ni3N, NiO and Ni2P) composites are prepared by mechanical ball-milling. The dehydrogenation properties of Mg-based composites are systematically studied using isothermal dehydrogenation apparatus, temperature-programmed desorption system and differential scanning calorimetry. It is experimentally confirmed that the dehydrogenation performance of the Mg-based materials ranks as following: MgH2/>Ni<sub>3</sub>C, MgH<sub>2</sub><img style=
Keywords:Hydrogen storage  Ni-based compounds  Hydrogen storage mechanism
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