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通过挤出-热拉伸制备CB/PET/PE导电复合材料
引用本文:许向彬,李忠明,芦艾,干劲玲,杨鸣波,黄锐. 通过挤出-热拉伸制备CB/PET/PE导电复合材料[J]. 高分子材料科学与工程, 2004, 20(4): 146-148,152
作者姓名:许向彬  李忠明  芦艾  干劲玲  杨鸣波  黄锐
作者单位:1. 四川大学高分子科学与工程学院,高分子材料工程国家重点实验室,四川,成都,610065
2. 四川大学高分子科学与工程学院,高分子材料工程国家重点实验室,四川,成都,610065;中国工程物理研究院化工材料研究所,四川,绵阳,621900
基金项目:国家自然科学基金(50103007),中国工程物理研究院科学基金资助项目
摘    要:
在前期热塑性塑料原位成纤研究基础上,尝试通过挤出-热拉伸制备原位微纤化炭黑(CB)/聚对幕二甲酸乙二醇酯(PET)/高密度聚乙烯(HDPE)导电复合材料。先将CB/PET熔融混合制成母料,再将母料和HDPE按一定的比例挤出一热拉伸。实验发现,体系成纤性能受母料的熔融粘度影响。在相对低的CB含量下,复合物能形成较好的原位微纤,从而具有较好的电性能.

关 键 词:挤出 热拉伸 制备 CB/PET/PE导电复合材料 炭黑 聚对苯二甲酸乙二醇酯 聚乙烯 原位成纤
文章编号:1000-7555(2004)04-0146-03

ELECTRICALLY CONDUCTIVE CB/PET/PE COMPOSITE PREPARED THROUGH EXTRUSION AND HOT STRETCHING
XU Xiang-bin,LI Zhong-ming,LU Ai. ELECTRICALLY CONDUCTIVE CB/PET/PE COMPOSITE PREPARED THROUGH EXTRUSION AND HOT STRETCHING[J]. Polymer Materials Science & Engineering, 2004, 20(4): 146-148,152
Authors:XU Xiang-bin  LI Zhong-ming  LU Ai
Affiliation:XU Xiang-bin~1,LI Zhong-ming~1,LU Ai~
Abstract:
Based on the previous study of in-situ fibrillation of general engineering plastics/general-purpose plastics, it was attempted to prepare fibrillar carbon black (CB)/poly(ethylene terephthalate) (PET)/polyethylene (PE) composite with electrical conductivity through extrusion and hot stretching. CB and PET were first melted mixed into masterbatch. Then, the mixture of CB/PET masterbatch and PE were extruded and hot stretched. It was found that the melt viscosity of masterbatch can affect the formation of in-situ fibers. As the CB loading is relatively low, the composite has obvious in-situ fibers and hence has correspondingly good conductivity.
Keywords:CB/PET/PE composite  in-situ fibrillation  morphology  electrical conductivity
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