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Non-Steady Equilibrium during Pro-Eutectoid Ferrite Formation in Fe-0.2C Alloy
作者姓名:ZHANG Hong bing  WU Rui heng  HSU T Y
作者单位:ZHANG Hong bing 1,WU Rui heng 2,HSU T Y(XU Zu yao) 2,RUAN Xue yu 2 (1. Shanghai Institute of Technology,Shanghai 200233,China; 2. Shanghai Jiaotong University,Shanghai 200030,China)
基金项目:ItemSponsoredbyNationalNaturalScienceFoundationofChina (50 0 750 53)
摘    要:Theprecipitationofpro eutectoidferritefromausteniteiscontrolledbydiffusioninFe Calloys .Withtheassumptionthatthemigratinginterfaceisalwaysinlocalequilibrium ,earlyin 194 9,ZenerC1] explainedthediffusionalgrowthofpro eutec toidferritebyusingtheFick’slaw .Since…

关 键 词:pro-eutectoid  ferrite  non-steady  diffusion  diffusion  velocity  Fick‘s  second  law

Non-Steady Equilibrium during Pro-Eutectoid Ferrite Formation in Fe-0.2C Alloy
ZHANG Hong bing ,WU Rui heng ,HSU T Y.Non-Steady Equilibrium during Pro-Eutectoid Ferrite Formation in Fe-0.2C Alloy[J].Journal of Iron and Steel Research,2002,9(2):28-32.
Authors:ZHANG Hong-bing  WU Rui-heng  HSU T Y  RUAN Xue-yu
Affiliation:1. Shanghai Institute of Technology, Shanghai 200233, China
2. Shanghai Jiaotong University, Shanghai 200030, China
Abstract:By using the Fick's second law, the carbon concentration of phase γ at non-equilibrium interface and its distribution in austenite during the decomposition of austenite to ferrite in Fe-C alloys were calculated. For example, it takes 160 sat 1 025 K, 210 s at 975 K, 270 s at 925 K and 580 s at 875 K for reaching the equilibrium carbon concentrations of phase γ at the α/γ interface in Fe-0.2C alloy, and the relationship between the ratio Cγ int/Cγ/α and the time meets the parabola law with parabola exponents of 0.167 39, 0.235 97, 0.319 87 and 0.389 44 at 1*!025 K, 975 K, 925 K and 875 K respectively. The decrease of the diffusion velocity of carbon in austenite with the increase of under-cooling would be counteracted by the increase of driving force for pro-eutectoid ferrite formation before soft impingement of ferrite grains with each other; but the effect of diffusion is more intensive than that of driving force at the later stage.
Keywords:pro  eutectoid ferrite  non  steady diffusion  diffusion velocity  Fick's second law
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