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GENERALIZED DERIVATIONS FOR MIXTURES USING THE VIRIAL EQUATION: APPLICATION TO FUGACITY
Authors:K.R. Hall   G. A. Iglesias-Silva
Affiliation:  a Chemical Engineering Department, Texas A&M University, College Station, TX, USA b Departmento de Ingenieria Quimica, Institute Tecnologico de Celaya, Celaya, GtoCP, MEXICO
Abstract:Calculation of mixture properties using the virial equation of state (VEOS) becomes tedious when the expression contains more than the second virial term. This paper describes a derivation procedure which permits relatively simple extension to any number of virial terms. We have used the fugacity derivation as an example of using the new technique and provide an equation for the fugacity coefficient using any number of terms and any number of components.
Keywords:Virial equation  Virial coefficients  Fugacity  Multicomponent
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