Diffusion-controlled chronoamperometry at a disk electrode |
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Authors: | Mahon Peter J Oldham Keith B |
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Affiliation: | Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia. mahon@rsc.anu.edu.au |
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Abstract: | An accurate formula exists for describing the decay of the current following the imposition of extreme concentration polarization on a disk electrode under diffusion-controlled conditions. It has been amply validated by diverse simulations and is presented here in a more compact form than hitherto. The formula finds application beyond the realm of potential-step chronoamperometry. |
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