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固相接枝聚丙烯的晶态结构和热行为
引用本文:解孝林,童身毅.固相接枝聚丙烯的晶态结构和热行为[J].武汉化工学院学报,1994(4).
作者姓名:解孝林  童身毅
作者单位:成都科技大学
摘    要:采用广角X射线衍射(WAXD)和差示扫描量热法(DSC),研究固相接枝反应对聚丙烯晶态结构和热行为的影响。结果表明聚丙烯用马来酸酐固相接枝后,晶面间距基本不变,微晶尺寸增大,熔点降低,结晶度略有提高。

关 键 词:聚丙烯  马来酸酐  固相接枝反应  晶态结构  热行为

Effect of Solid Phase Graft polymerization on Crystal Structure and Thermal Behaviour of Polypropylene
Xie Xiaolin, Tong Shenyi.Effect of Solid Phase Graft polymerization on Crystal Structure and Thermal Behaviour of Polypropylene[J].Journal of Wuhan Institute of Chemical Technology,1994(4).
Authors:Xie Xiaolin  Tong Shenyi
Affiliation:Xie Xiaolin; Tong Shenyi
Abstract:The effect of solid phase graft copolymerization on crystal structure and thermal behaviour of polypropylene was studied by WAXD and DSC method. The results show that the crystallite sizes of polypropylene increase due to the solid phase graft copolymerization of maleic anhydride, but the crystallographic interplanar spacing invaries. Moreover, the melting point of modified polypropylene depresses, and its crystallity slightly increases.
Keywords:Polypropylene  Maleic anhydride  Solid phase graft copolymerization  Crystal structure  Thermal behaviour
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