Supercritical fluid extraction and chromatography of emulsifiers |
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Authors: | William E Artz Michelle R Myers |
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Affiliation: | (1) Dept. of Food Science, University of Illinois, 382 Agr. Eng. Sci. Bldg., 1304 W. Pennsylvania Ave., 61801-4726 Urbana, IL |
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Abstract: | Selected emulsifiers, which included acetylated monoglycerides, lactylated monoglycerides, hexaglycerol distearate, triglycerol
mono/dioleate and decaglycerol decaoleate, were separated with capillary supercritical fluid chromatography on a 25% cyanopropyl
stationary phase with a mobile phase of CO2 at 100–150°C. In general, the density/pressure programs that produced the best separations were those with reduced pressure/density
ramp rates, which encompassed the largest possible pressure or density range. Samples of acetylated monoglycerides were placed
in a supercritical fluid extraction cell on a glass bead bed and extracted for 15 min at 50°C at 340, 408, 544 and 680 atm
with CO2. At 544 atm, 103.6 ± 1.0% of the emulsifiers was extracted. Acetylated monoglycerides were added during twin-screw extrusion
of cornstarch (3% w/w emulsifier/corn starch). The acetylated monoglycerides were extracted from the cornstarch extrudate
for 15 and 45 min, at 544 and 646 atm and 50–120°C with 0 and 5% added methanol. The percent acetylated monoglyceride extracted
after 45 min at 120°C and 646 atm was 60.0 ± 5.7%, while the amount extracted during a 7.5-h Soxtec extraction ranged from
17.9 to 29.4%, depending upon the solvent used. |
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Keywords: | Acetylated monoglycerides decaglycerol decaoleate emulsifiers hexaglycerol distearate lactylated monoglycerides supercritical fluid chromatography supercritical fluid extraction triglycerol mono/dioleate |
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