The oxidation state of sulfur detected in Na2O-CaO-SiO2 float glass by X-ray absorption near edge structure spectra |
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| Authors: | Zheng Meng Hong Jiang Yourong Huang Changjiu Li Jinzhen Wang Zhu Cui |
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| Affiliation: | 1. China Building Materials Academy, Beijing, 100024, China
2. College of Materials and Chemical Engineering, Hainan University, Haikou, 570228, China
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| Abstract: | The oxidation state of sulfur is detected in Na2O-CaO-SiO2 float glass by synchrotron radiation X-ray absorption near edge structure (XANES) spectra at the sulfur K edge. The measured spectra show the only presence of S6+ in the Na2O-CaO-SiO2 float glass and the oxidation state of sulfur do not change with the increase of glass depth. It is also found that, after the melt has gone through the molten tin bath, the S6+ is the dominant species, but S2? is also present on both surfaces. It is not certain whether cation bonds to S2? or not, because there are many cations dissolved in the melted tin which makes the spectrum complicated. |
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