Microstructure and Wear Behaviors of Plasma-Sprayed FeCrNiMoCBSi Coating with Nano-Grain Dispersed Amorphous Phase in Reciprocating Sliding Contact

A novel FeCrNiMoCBSi amorphous/nanocrystalline coating was fabricated using a plasma spraying process. The coating was dense with a low porosity of approximately 0.99%. The coating consisted of a 67.8 vol% amorphous phase coupled with many nanocrystalline grains that were approximately 5?nm in diameter. The mechanical properties of the as-sprayed coating were determined by nanoindentation measurement, and the tribological behaviors were systematically investigated in a reciprocating sliding contact. The results show that FeCrNiMoCBSi coatings possess superior wear resistance compared to other typically similar Fe-based amorphous coatings. The tribological behaviors evolve with the combination of normal load and sliding velocity. Herein, the dominant wear mechanisms are delamination wear and oxidation wear. With an increase in normal load and sliding velocity, the abrasive wear is gradually weakened, the formation of oxide films on the worn surfaces is facilitated, and wear debris is ground to powder. The oxide films suffer from fatigue wear with induced cracks undergoing reciprocating sliding effects.