| 添加纳米IrO_2的新型涂层IrO_2-Ta_2O_5钛阳极的制备及性能 |
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| 引用本文： | 白少金,魏宗平,王欣,邵艳群,唐电.添加纳米IrO_2的新型涂层IrO_2-Ta_2O_5钛阳极的制备及性能[J].中国有色金属学报,2011,21(3). |
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| 作者姓名： | 白少金 魏宗平 王欣 邵艳群 唐电 |
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| 作者单位： | 福州大学材料研究所,福州,350108 |
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| 基金项目： | 国家重点基础研究发展计划资助项目(2007AA03Z325); 福建省自然科学基金资助项目(2009J05116) |
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| 摘 要： | 以纳米IrO2晶粒部分取代H2IrCl6分散于前躯体溶液中,以此改进工艺制备一种Ir和Ta的摩尔比为7-3的IrO2-Ta2O5涂层钛阳极,通过XRD和SEM分析所制备钛阳极表面涂层的物相组成和形貌特征,采用析O2极化曲线、循环伏安和强化寿命测试方法分别研究电极的电催化性能与稳定性。结果表明:在纳米种子嵌入电极涂层中存在的物相分别为IrO2基固溶体(Ir,Ta)O2和IrO2;与采用传统方法制备的电极相比,含纳米种子嵌入结构涂层的钛阳极具有更优越的电催化活性和耐蚀性。
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| 关 键 词： | IrO2 Ta2O5 钛阳极 纳米种子 电催化性能 |
Preparation and performance of novel IrO_2-Ta_2O_5 coated titanium anode with embedded nanoscale IrO_2 |
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| BAI Shao-jin,WEI Zong-ping,WANG Xin,SHAO Yan-qun,TANG Dian.Preparation and performance of novel IrO_2-Ta_2O_5 coated titanium anode with embedded nanoscale IrO_2[J].The Chinese Journal of Nonferrous Metals,2011,21(3). |
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| Authors: | BAI Shao-jin WEI Zong-ping WANG Xin SHAO Yan-qun TANG Dian |
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| Affiliation: | BAI Shao-jin,WEI Zong-ping,WANG Xin,SHAO Yan-qun,TANG Dian(Institute for Materials Research,Fuzhou University,Fuzhou 350108,China) |
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| Abstract: | An IrO2-Ta2O5/Ti anode coating with molar ratio of Ir to Ta of 7:3 on titanium was prepared by a modified technology,in which a portion of nano-crystalline of IrO2 was introduced to replace some amount of H2IrCl6 in the precursor solution.The phase structure and morphology of the coating were analyzed by X-ray diffractometry(XRD) and scanning electronic microscopy(SEM),respectively.The electro-catalytic properties and electrochemical stability of the coating were also characterized by using O2 evolution pol... |
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| Keywords: | IrO2 Ta2O5 titanium anode nano-seeds electro-catalytic properties |
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