| 尼龙6固相聚合建模与计算机仿真 |
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| 引用本文： | 谢建军,唐志廉.尼龙6固相聚合建模与计算机仿真[J].化学反应工程与工艺,2000,16(4):374-382. |
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| 作者姓名： | 谢建军 唐志廉 |
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| 作者单位： | 1. 湘潭大学高分子材料研究所,湖南,湘潭,411105
2. 中国纺织大学环境系,上海,200051 |
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| 基金项目： | 中国博士后科学基金，湖南省教育厅科研项目，中博基[1997]1 1号文，99C111，， |
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| 摘 要： | 在一定假设基础上建立了尼龙６固相聚合过程模，并用实验数据验证了模型的正确性，结果表明随着固相聚合时间的延长，数均聚合度Ｕｎ增加。
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| 关 键 词： | 尼龙6 固相聚合 模型化 计算机仿真 |
| 修稿时间： | 1999-09-24 |
MODELING FOR SOLID-STATE POLYMERIZATION OF NYLON 6 |
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| XIE Jian-jun,TANG Zhi-lian.MODELING FOR SOLID-STATE POLYMERIZATION OF NYLON 6[J].Chemical Reaction Engineering and Technology,2000,16(4):374-382. |
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| Authors: | XIE Jian-jun TANG Zhi-lian |
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| Abstract: | A model for solid-state polymerization (SSP) of nylon 6 was proposed in this
paper. It was verified by comparing the simulated and the experimental data. On the base,
the effect of affecting factor s, such as the temperature and the time, the diameter of
particles, the initial Un of the prepolymer, the initial concentrations of the water, the
monomer (capr olactam), the aminocaproic acid, the regulator of the relative molecular
weight, on the average Un in the radius direction for SSP of nylon 6 were analyzed. |
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| Keywords: | Nylon 6 solid-state polymeriza tion modeling |
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