| 非对称花四羧酰单亚胺染料系列光电性能研究 |
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| 引用本文： | 刘翀,胡友波,张俭平.非对称花四羧酰单亚胺染料系列光电性能研究[J].化学工程师,2010,24(2):63-66. |
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| 作者姓名： | 刘翀 胡友波 张俭平 |
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| 作者单位： | 1. 黑龙江科技学院,现代分析测试研究中心,黑龙江,哈尔滨,150027
2. 黑龙江省质量监督检测研究院,黑龙江,哈尔滨,180050 |
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| 摘 要： | 本文合成了一系列不同氨基取代的非对称茈四羧酰单亚胺化合物，并将它们分别组装到TiO2纳米晶电极上，通过红外光谱、荧光发射光谱、光电化学测试等表征手段，对其光电化学性质进行了比较研究，结果发现，它们分子结构中胺基取代基的结构及吸或推电子能力与自身的光电性质存在着一定的关系和规律。
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| 关 键 词： | 非对称 四羧酰单亚胺 光电性质 光谱 |
Research of photoelectric properties for dimide derivatives of 3,4,9,10-perylenetetracarboxylic dianhydrid |
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| LIU Chong,HU You-bo,ZHANG Jian-ping.Research of photoelectric properties for dimide derivatives of 3,4,9,10-perylenetetracarboxylic dianhydrid[J].Chemical Engineer,2010,24(2):63-66. |
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| Authors: | LIU Chong HU You-bo ZHANG Jian-ping |
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| Affiliation: | 1.School of Chemistry and Materials Science;Heilongjiang University;Harbin 150080;China;2.Heilongjiang Academy of Quality Supervision & Inspection;Harbin 150050;China |
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| Abstract: | A series of Di(aminoacid)imide derivatives of 3,4,9,10-perylene tetracarboxylic dianhydride were synthesized and self-assembled on nanocrystalline TiO2 electrodes.The research for their photoelectric properties is carried out by means of IR,fluorescence emission spectroscopy,electrochemical determination and so on.The experimental results demonstrate that the relationship and certain rule must exist between molecular structure and photoelectric properties. |
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| Keywords: | dissymmetry 3 4 9 10-perylenetetracarbexylic dianhydrid photoelectric properties |
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