Ionic mass transfer in parallel plate electrochemical cells

Experimental investigations have been made of ionic mass transfer in a parallel plate electrochemical cell under both laminar and turbulent flow. The results obtained in the laminar flow region were found to be well represented by a Leveque-type equation modified to include the cell aspect ratio as an additional parameter. The influence of decreased mass transfer at the edges of the electrodes due to changes in the velocity profile was found to be small. For the turbulent region, there is a correlation of the mass transfer coefficient with Reynolds number to an exponent of 0.875 and Schmidt number to exponent of 0.21. This is in accord with existing correlations for heat and mass transfer in similar geometries over the range studied.