| 磷钨酸/硅胶催化剂催化合成环己酮乙二醇缩酮 |
| |
| 引用本文： | 吕宝兰,黎杉珊,杨水金.磷钨酸/硅胶催化剂催化合成环己酮乙二醇缩酮[J].精细石油化工进展,2011,12(12):50-52. |
| |
| 作者姓名： | 吕宝兰 黎杉珊 杨水金 |
| |
| 作者单位： | 湖北师范学院化学与环境工程学院,黄石,435002 |
| |
| 摘 要： | 以环己酮和乙二醇为原料合成环己酮乙二醇缩酮,考察了磷钨酸/硅胶催化剂对缩酮反应的催化活性.结果表明,磷钨酸/硅胶催化剂是合成环己酮乙二醇缩酮的良好催化剂,确定了最佳合成条件:n(环己酮):n(乙二醇)=1:1.4,磷钨酸/硅胶催化剂用量为反应物总质量的0.2％,带水剂环己烷用量为8mL,反应时间为30 min.在此条件...
|
| 关 键 词： | 环己酮乙二醇缩酮 磷钨酸 硅胶 催化 缩酮反应 |
Catalytic Synthesis of Cyclohexanone Ethylene Ketal over Phosphotungstic Acid/silica Gel |
| |
| Lü Baolan,Li Shanshan,Yang Shuijin.Catalytic Synthesis of Cyclohexanone Ethylene Ketal over Phosphotungstic Acid/silica Gel[J].Advances in Fine Petrochemicals,2011,12(12):50-52. |
| |
| Authors: | Lü Baolan Li Shanshan Yang Shuijin |
| |
| Affiliation: | Lti Baolan Li Shanshan Yang Shuijin (College of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002) |
| |
| Abstract: | Cyclohexanone ethylene ketal was synthesized with cyelohexanone and glycol as the materials, and the catalytic activity of phosphotungstic acid/silica gel catalyst in ketol reaction was studied. According to the results, silicotungstic acid/silica gel （SG） is a good catalyst for the synthesis of cyclohexanone ethylene ketal. The optimum synthesis conditions were identified： n （cyclohexanone） ： n （glycol） = 1： 1.4, amount of watercarrying agent （i. e. cyclohexane） ： 8 mL, reaction time： 30 min. The yield of cyclohexanone ethylene ketal can reach 76.4% at such conditions. |
| |
| Keywords: | cyclohexanone ethylene ketal phosphotungstic acid silica gel catalysis ketal reaction |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
