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抗氧剂SKY-1035合成工艺及应用研究
引用本文:郑忻,夏飞,李杰.抗氧剂SKY-1035合成工艺及应用研究[J].精细与专用化学品,2007,15(6):19-22.
作者姓名:郑忻  夏飞  李杰
作者单位:1. 北京加成助剂研究所,北京100078
2. 北京加成助剂研究所,北京100078;北京化工三厂,北京100078
摘    要:以硫二甘醇和3,5-二叔丁基-4-羟基苯基丙烯酸甲酯为原料,合成了新型抗氧剂——2,2’-硫代双3-(3,5-二叔丁基-4-羟基苯基)丙酸乙酯](简称SKY-1035),并讨论了原料配比、真空度和温度等因素对产率的影响。将该产品应用于交联聚乙烯绝缘料等塑料材料中进行试验,获得了较好的抗氧化结果,且合成工艺合理、产品质量稳定,具有良好的应用前景。

关 键 词:抗氧剂  硫二甘醇  交联聚乙烯  合成工艺
修稿时间:2007年2月9日

Synthesis and Application of Antioxidant SKY-1035
ZHENG Xin,XIA Fei,LI Jie.Synthesis and Application of Antioxidant SKY-1035[J].Fine and Specialty Chemicals,2007,15(6):19-22.
Authors:ZHENG Xin  XIA Fei  LI Jie
Abstract:Using thiodiglycol and 3,5-di-tert-butyl-4-hydroxyphenyl methyl acrylate as raw material, the new antioxidant, 2,2-thiobisethyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate](abbreviated as SKY-1035) was synthesized. The factors influencing on the yield were discussed, such as ratio of raw materials, degree of vacuum, reaction temperature, and so on. The good anti-oxidant results were shown when the product was applied to cross-linking PE insulator or other plastic materials. It was pointed out that the preparation technology was reasonable, quality of the product was stable, hence the prospect of application would wide.
Keywords:antioxidant  thiodiglycol  cross-linking PE  preparation technology
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