Characterization and biodegradability of amphoteric superabsorbent polymers

Novel amphoteric superabsorbent polymers (SAPs) based on carboxymethyl cellulose, acrylic acid, acrylamide, and [2‐(methylacryloyloxy)ethyl]trimethylammonium chloride were prepared by inverse suspension copolymerization. The SAPs were characterized by Fourier transforms infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy. The absorbency or swelling behaviors in deionized water, saline solutions, and pH value solutions were investigated. Experimental results indicate that the absorbency in various solutions decreases with an increase of the ion concentration, which was attributed to osmotic pressure of water and ions between the polymeric gel and the external solutions. Biodegradability of the amphoteric SAPs was also reported. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008