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| 1,2,3-三硝基氮杂环丁烷溶析结晶动力学研究 | |
| 引用本文： | 胡金伟,王建龙,陈丽珍. 1,2,3-三硝基氮杂环丁烷溶析结晶动力学研究[J]. 上海化工, 2011, 0(6): 7-9 |
| 作者姓名： | 胡金伟 王建龙 陈丽珍 |
| 作者单位： | 中北大学,太原,030050 |
| 摘 要： | 基于分级法[1]求解了TNAZ间歇溶析结晶过程的粒数衡算方程,通过激光粒度分布测量仪测量了结晶过程中粒度分布随不同温度、搅拌强度、溶析剂滴加速率的变化规律。利用已建立的TNAZ间歇溶析结晶过程的粒数衡算方程求解模型得到了生长动力学参数,最后用最小二乘法模拟出了成核速率和生长速率方程[2]。成核速率和生长速率是结晶模拟过程中最核心的控制条件。 |
| 关 键 词： | TNAZ 成核速率 生长速率 分级法 溶析结晶 |
Investigation on TNAZ Solventing Kinetics of Crystallization |
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| Hu Jinwei,Wang Jianlong,Chen Lizhen. Investigation on TNAZ Solventing Kinetics of Crystallization[J]. Shanghai Chemical Industry, 2011, 0(6): 7-9 | |
| Authors: | Hu Jinwei Wang Jianlong Chen Lizhen |
| Affiliation: | Hu Jinwei Wang Jianlong Chen Lizhen |
| Abstract: | Based on the classification method we established population balance of periodic crystallization,also got the variation of Particle size distribution with Temperature,Stir intensity and drop rate of speed of anti-solvent by means of laser particle size distribution measuring instrument.The growth dynamic parameters were solved by using population balance mathematic model,and then fitted the rate of nucleation and growth by Least-square technique.The nucleation rate and growth rate equation are the most cruc... |
| Keywords: | TNAZ Nucleation rate Growth rate Classification method Anti-solvent crystallization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |