| AlCl3改性阳离子交换树脂催化合成异丙叉甘油 |
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| 引用本文： | 李晓燕,肖国民,魏瑞平,葛冬娟.AlCl3改性阳离子交换树脂催化合成异丙叉甘油[J].过程工程学报,2008,8(2):263-266. |
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| 作者姓名： | 李晓燕 肖国民 魏瑞平 葛冬娟 |
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| 作者单位： | 东南大学化学化工学院 东南大学化学化工学院 东南大学化学化工学院 东南大学化学化工学院 |
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| 基金项目： | 江苏省高技术研究重大基金资助项目(编号:BG2006034) |
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| 摘 要： | 以无水AlCl3、阳离子交换树脂和AlCl3改性阳离子交换树脂为催化剂，对丙三醇与丙酮缩合反应进行了研究，AlCl3改性阳离子交换树脂对反应的催化效果最佳. Hammett指示剂法和吡啶吸附红外表征结果表明，采用AlCl3对阳离子交换树脂进行改性后，催化剂的酸强度有所提高，催化活性增强. AlCl3改性阳离子交换树脂催化合成异丙叉甘油的优化反应条件为：反应温度82℃，n丙三醇/n丙酮=1:3，催化剂用量为丙三醇质量的10%，反应时间11 h，异丙叉甘油收率为90.9%.
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| 关 键 词： | 丙三醇 异丙叉甘油 无水AlCl3 阳离子交换树脂 AlCl3改性阳离子交换树脂 |
| 文章编号： | 1009-606X(2008)02-0263-04 |
| 收稿时间： | 2007-08-31 |
| 修稿时间： | 2007年8月31日 |
Synthesis of 1,2-Isopropylidene Glycerol with Cation Exchange Resin Modified by AlCl3 |
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| LI Xiao-yan,XIAO Guo-min,WEI Rui-ping,GE Dong-juan.Synthesis of 1,2-Isopropylidene Glycerol with Cation Exchange Resin Modified by AlCl3[J].Chinese Journal of Process Engineering,2008,8(2):263-266. |
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| Authors: | LI Xiao-yan XIAO Guo-min WEI Rui-ping GE Dong-juan |
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| Affiliation: | School of Chemistry and Chemical Engineering，Southeast University School of Chemistry and Chemical Engineering，Southeast University School of Chemistry and Chemical Engineering，Southeast University School of Chemistry and Chemical Engineering，Southeast University |
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| Abstract: | Anhydrous AlCl3, cation exchange resin and cation exchange resin modified by AlCl3 were investigated in condensation of glycerol and acetone. As shown in the results of Hammett indicator and pyridine adsorption infrared spectra, the acid strength and catalytic activity of the cation exchange resin were improved after being modified by AlCl3. The highest yield (90.9%) of 1,2-isopropylidene glycerol was obtained under the conditions of molar ratio of glycerol to acetone of 1:3, catalyst concentration of 10%(w), reaction time of 11 h, and 82℃ temperature with the catalyst cation exchange resin modified by AlCl3. |
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| Keywords: | glycerol 2-isopropylidene glycerol anhydrous AlCl3 cation exchange resin cation exchange resin modified by AlCl3 |
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