Fabrication of super flux and high thermal shock resistance ceramic membrane support |
| |
Authors: | Wenmin Zhang Kang Guan Defang Liu Cheng Peng Jianqing Wu |
| |
Affiliation: | School of Material Science and Engineering, South China University of Technology, Guangzhou 510630, China |
| |
Abstract: | Ceramic membranes play an important role in high temperature gas-solid filtration. However, the thermal stability of the ceramic support at high temperatures has always been a problem. In this study, porous fused silica ceramic supports were fabricated with hexagonal boron nitride as a sintering aid. The results shown that hexagonal boron nitride could inhibit the crystallization of fused silica ceramic particles at high temperature and act as a sintering addictive to reduce firing temperature. The obtained supports have an average pore size of 72?µm, an open porosity of 42%, a bending strength of 16.5?MPa, a Weibull modulus of 8.67 and a gas permeability of 4.23?×?105 m3/(m2 h bar). The bending strength of the support remained 16?MPa after 30 cold-hot cycles, exhibiting high thermal shock resistance. After corrosion in 20?vol% H2SO4 solution for 8?h, the weight and the bending strength of the support were diminished by 0.6% and 24.32%, respectively. So, the ceramic support showed good acid corrosion resistance. |
| |
Keywords: | Fused silica ceramic Hexagonal boron nitride Crystallization Super flux High thermal shock resistance |
本文献已被 ScienceDirect 等数据库收录! |
|