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Synthesis and characterization of HDA/NaMMT organoclay
Authors:C. Yürdü  S. Işçi  C. Ünlü  O. Atici  Ö. I. Ece  N. Güngör
Affiliation:(1) Department of Physics, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey;(2) Department of Chemistry, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey;(3) Department of Geology, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey
Abstract:In this study, the rheologic and colloidal characterizations of sodium montmorillonite (NaMMT) were examined. Hexadecylamine (CH3(CH2)15NH2, HDA) was added to the bentonite water dispersion (2%, w/w) in different concentrations in the range 5.6 × 10−4−9.4 × 10−3 mmol/l. The rheological and electrokinetic behaviour of aqueous montmorillonite dispersions was investigated as a function of solid content and HDA concentration. The basal spacings of the HDA/NaMMT composites were studied by X-ray diffraction. The FTIR spectra were obtained from the modified bentonite products, which revealed the characteristic absorbances after treatment with HDA.
Keywords:Montmorillonite    hexadecylamine    organoclay
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