| 硅胶负载硅钨酸催化合成丁酮1，2-丙二醇缩酮 |
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| 引用本文： | 朱珍珠,江海英,杨水金.硅胶负载硅钨酸催化合成丁酮1，2-丙二醇缩酮[J].精细石油化工进展,2010,11(6):26-28. |
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| 作者姓名： | 朱珍珠 江海英 杨水金 |
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| 作者单位： | 湖北师范学院化学与环境工程学院,黄石,435002 |
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| 基金项目： | 湖北师范学院大学生科研基金资助项目 |
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| 摘 要： | 以硅胶负载硅钨酸为催化剂，以丁酮和1，2-丙二醇为原料催化合成丁酮1，2丙二醇缩酮。考察了丁酮与1，2-丙二醇物质的量比、催化剂用量、带水剂及反应时间对收率的影响。结果表明，在n（丁酮）：n（1，2-丙二醇）=1：1．5，催化剂用量为反应物料总质量的1．0％，带水剂环己烷10mL，反应时间1h的优化条件下，丁酮1，2-丙二醇缩酮的收率可达77．3％。
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| 关 键 词： | 丁酮1，2-丙二醇缩酮 硅胶 硅钨酸 催化 缩酮反应 |
Catalytic Synthesis of Butanone-1,2-Propanediol Ketal with Silica Gel Supported Silicotungstic Acid |
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| Zhu Zhenzhu,Jiang Haiying,Yang Shuijin.Catalytic Synthesis of Butanone-1,2-Propanediol Ketal with Silica Gel Supported Silicotungstic Acid[J].Advances in Fine Petrochemicals,2010,11(6):26-28. |
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| Authors: | Zhu Zhenzhu Jiang Haiying Yang Shuijin |
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| Affiliation: | Zhu Zhenzhu Jiang Haiying Yang Shuijin (Chemistry and Environment Engineering Institute of Hubei Normal University, Huangshi 435002) |
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| Abstract: | Butanone - 1,2 - propanediol ketal was synthesized chemically with silica gel supported silicotungstic acid as the catalyst and butanone and 1,2 - propanediol as the feedstock. The effect of mass ratio of butanone to 1, 2 - propanediol, catalyst consumption, water carrying agent and reaction time on the yield was studied. The results have shown that the yield of butanone - 1,2 - propanediol ketal can reach 77.3% at the optimized conditions, i.e. n（butanone） ： n （ 1,2 - propanediol） = 1 ： 1.5, catalyst consumption accounts for 1.0% of total mass of reactants, and reaction time is 1 h. |
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| Keywords: | butanone - 1 2 - propanediol ketal silica gel silicotungstic acid catalysis ketal reaction |
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