| 环戊二烯加氢制环戊烯的工艺条件优化研究 |
| |
| 引用本文： | 赵巍,赵素娟,臧娜,陈兴.环戊二烯加氢制环戊烯的工艺条件优化研究[J].精细化工中间体,2013(4):54-56. |
| |
| 作者姓名： | 赵巍 赵素娟 臧娜 陈兴 |
| |
| 作者单位： | 中钢集团鞍山热能研究院有限公司研发中心,辽宁鞍山114000 |
| |
| 摘 要： | 以环戊二烯为原料,使用PdCl3为催化剂,甲苯为溶剂,采用间歇式高压反应釜,常温条件加氢制备环戊烯。采用正交实验对环戊二烯加氢过程进行研究,确定了反应温度、催化剂用量、压力、反应时间等因素对加氢过程的影响。优化工艺条件为:反应温度25℃,催化剂比例1.0%(m/m),压力1.5 MPa,反应时间4 h,此时环戊烯的收率达85.5%。
|
| 关 键 词： | 环戊二烯 加氢 正交实验 |
Study on Preparation of Cyclopentene by Hydrogenation of Cyclopentadiene |
| |
| ZHAO Wei,ZHAOSu-juan,ZANGNa,CHENXing.Study on Preparation of Cyclopentene by Hydrogenation of Cyclopentadiene[J].Fine Chemical Intermediates,2013(4):54-56. |
| |
| Authors: | ZHAO Wei ZHAOSu-juan ZANGNa CHENXing |
| |
| Affiliation: | (Sinosteel Anshan Research Institute of Thermo-energy Co., Ltd, Anshan 114000, China) |
| |
| Abstract: | Cyclopentene was prepared by PdC13 catalyzed hydrogenation of cyclopentadiene in toluene under pressure at room temperature. The reaction conditions were optimized on basis of orthogonal experiments：reaction temperature of 25℃ ,load of catalyst of 1.0 % （mass）,hydrogen pressure of 1.5 MPa,reaction time of 4 hours. The yield of cyclopentene was 85.5%. |
| |
| Keywords: | cyclopentadiene hydrogenation orthogonal experiment |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
