| 聚叠氮缩水甘油醚的合成与改性研究进展 |
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| 引用本文： | 王旭朋,罗运军,郭凯,吕勇. 聚叠氮缩水甘油醚的合成与改性研究进展[J]. 精细化工, 2009, 26(8) |
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| 作者姓名： | 王旭朋 罗运军 郭凯 吕勇 |
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| 作者单位： | 北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081;北京理工大学,材料科学与工程学院,北京,100081 |
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| 摘 要： | 聚叠氮缩水甘油醚(GAP)是国内外重点研究的含能粘合剂之一。该文综述了GAP的合成研究进展,重点介绍了高相对分子质量GAP、支化GAP和等规GAP的合成。针对GAP反应活性低的特点,介绍了GAP的多种端基改性方法。GAP的无规、嵌段共聚物改善了GAP粘合剂的性能,GAP与其他粘合剂的互穿及共混,为GAP在推进剂中的应用提供了广阔前景。引用文献37篇。
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| 关 键 词： | 聚叠氮缩水甘油醚 含能粘合剂 改性 |
Research Advances in Synthesis and Modification of Glycidyl Azide Polymer |
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| WANG Xu-peng,LUO Yun-jun,GUO Kai,LV Yong. Research Advances in Synthesis and Modification of Glycidyl Azide Polymer[J]. Fine Chemicals, 2009, 26(8) |
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| Authors: | WANG Xu-peng LUO Yun-jun GUO Kai LV Yong |
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| Affiliation: | School of Materials Science and Engineering;Beijing University of Technology;Beijing 100081;China |
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| Abstract: | Glycidyl Azide Polymer(GAP)is one of the energetic binders for high energy propellants being researched emphatically at home and abroad in the latest period.Synthetic methods and new advances of GAP were reviewed.In particular,the syntheses of high molecular GAP、B-GAP and isotactic GAP were summarized.Methods of Modified GAP were introduced for the low reactivity of GAP.The random and block copolymerization of GAP improved the properties of GAP.The interpenetrating network and blend of GAP with other binders promoted GAP to be used in propellants.37 references are cited. |
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| Keywords: | glycidyl azide polymer energetic binder modification |
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