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褐煤煤尘爆炸火焰传播特性及燃烧热分解机理研究
引用本文:刘静平,杨振欣,赵懿明,刘毅飞,吴星亮,徐司雨,徐森. 褐煤煤尘爆炸火焰传播特性及燃烧热分解机理研究[J]. 爆破器材, 2022, 51(6): 16-21. DOI: 10.3969/j.issn.1001-8352.2022.06.003
作者姓名:刘静平  杨振欣  赵懿明  刘毅飞  吴星亮  徐司雨  徐森
作者单位:①南京理工大学化学与化工学院(江苏南京,210094)②中北大学环境与安全工程学院(山西太原,030051)③西安近代化学研究所燃烧与爆炸技术重点实验室(陕西西安,710065)
摘    要:煤尘爆炸是矿井安全开采的主要危险源之一。以褐煤煤尘为研究对象,探究煤尘粒径对煤尘火焰传播过程的影响。用高速摄影装置记录火焰的传播过程,进而分析不同粒径下煤尘爆炸火焰传播的高度和速度。为进一步分析煤尘燃烧过程中的化学反应机理,借助反应分子动力学方法对煤分子燃烧中的初始热分解过程进行了模拟。研究结果表明:爆炸火焰传播高度呈先增加、后稳定的趋势,传播速度呈先增大、后减小的趋势;随着煤尘粒径的减小,火焰传播高度和传播速度均呈增大的趋势;当煤尘粒径为10.5 μm时,火焰传播高度和传播速度的峰值分别为623 mm和4.3 m/s;煤尘热分解主要产物为H2、H2O、CO2和CH2O,这些产物进一步与氧气的结合会促进煤尘燃烧和火焰传播过程,使得整个体系燃速加快。为煤尘热分解和燃烧提供了较为充分的数据基础。

关 键 词:褐煤煤尘  粉尘粒径  火焰传播  爆炸过程  分子动力学

Study on Flame Propagation Characteristics and Combustion Pyrolysis Mechanism of Lignite Dust Explosion
LIU Jingping,YANG Zhenxin,ZHAO Yiming,LIU Yifei,WU Xingliang,XU Siyu,XU Sen. Study on Flame Propagation Characteristics and Combustion Pyrolysis Mechanism of Lignite Dust Explosion[J]. Explosive Materials, 2022, 51(6): 16-21. DOI: 10.3969/j.issn.1001-8352.2022.06.003
Authors:LIU Jingping  YANG Zhenxin  ZHAO Yiming  LIU Yifei  WU Xingliang  XU Siyu  XU Sen
Affiliation:①School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)②School of Environment and Safety Engineering, North University of China (Shanxi Taiyuan, 030051)③Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
Abstract:Coal dust explosion is one of the main hazard sources for safe mining in mines. Taking lignite dust as the research object to explore the effect of dust particle size on the coal dust flame propagation. The flame propagation was recorded by a high-speed camera, and the height and velocity of flame propagation in coal dust explosion under different particle sizes were analyzed. To further analyze the chemical reaction mechanism during the combustion of coal dust, the initial pyrolysis process of coal molecules in combustion was simulated through reactive molecular dynamics. Results show that propagation height of flame increases first and then stabilizes, and propagation velocity increasesfirst and then decreases. With the decrease of the particle size of coal dust, the flame propagation height and propagation velocity both show an increasing trend. When the particle size is 10.5 μm, the flame propagation height peak and propagation velocity peak are 623 mm and 4.3 m/s, respectively. The main products of coal dust pyrolysis are H2, H2O, CO2, and CH2O, and the further combination of these products with oxygen will promote the combustion and flame propagation of coal dust, so that the combustion rate of the whole system is accelerated. It provids a sufficient data support for coal dust pyrolysis and combustion.
Keywords:lignite dust  dust particle size  flame propagation  explosion process  molecular dynamics
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