| 可逆加成-断裂链转移自由基聚合的新进展 |
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| 引用本文： | 娄宇,胡娜,李继航,陈明清.可逆加成-断裂链转移自由基聚合的新进展[J].化学世界,2010,51(8). |
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| 作者姓名： | 娄宇 胡娜 李继航 陈明清 |
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| 作者单位： | 江南大学化学与材料工程学院,江苏,无锡,214122 |
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| 基金项目： | 国家自然科学基金，江苏高等学校科技创新团队 |
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| 摘 要： | 可逆加成-断裂链转移(RAFT)自由基聚合的适用单体范围广,反应条件温和,没有聚合实施方法如本体、溶液、乳液和悬浮聚合的限制,因而引起了研究者的广泛兴趣,取得了许多新的研究成果。主要对近年来RAFT聚合中使用的最新链转移剂、单体及相关合成与使用情况以及几种新型RAFT反应体系进行了介绍。
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| 关 键 词： | 可逆加成-断裂链转移 自由基聚合 链转移剂 新型RAFT体系 |
Recent Advances of Reversible Addition Fragmentation Chain-Transfer Polymerization |
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| LOU Yu,HU Na,LI Ji-hang,CHEN Ming-qing.Recent Advances of Reversible Addition Fragmentation Chain-Transfer Polymerization[J].Chemical World,2010,51(8). |
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| Authors: | LOU Yu HU Na LI Ji-hang CHEN Ming-qing |
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| Abstract: | Reversible addition fragmentation chain-transfer (RAFT) polymerization is compatible with a wide range of monomers and mild reaction conditions,and there is no constraints in implementation of methods such as bulk,solution,emulsion and suspension polymerization constrains which has attracted much interest of the researchers.The new chain transfer agents and monomers and used of RAFT polymerization and several new types of RAFT reaction systems are introduced. |
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| Keywords: | RAFT living radical polymerization chain-transfer agent new RAFT reaction system |
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