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An acid catalyzed step in the catalytic reduction of NO x to N2
Authors:Meijun Li  Younghoon Yeom  Eric Weitz  Wolfgang M. H. Sachtler
Affiliation:(1) Department of Chemistry and Institute for Catalysis in Energy Processes, Northwestern University, Evanston, IL 60208-3113, USA;(2) V. N. Ipatieff Laboratory, Center for Catalysis and Surface Science, Northwestern University, 2137 Tech Drive, Evanston, IL 60208, USA
Abstract:Contact of adsorbed ammonium nitrite, NH4NO2, with HCl vapor or a solid acid such as the zeolite HY, significantly lowers the temperature of its decomposition to N2 + H2O. Protonated NH4NO2 decomposes at room temperature. The decomposition of ammonium nitrite is one of the steps in the catalytic reduction of NO x with ammonia or other reductants.
Keywords:NO x reduction  ammonium nitrite decomposition  Ba/Y  zeolite catalysts
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