Water Vapour Effects on FeO Scale Growth: Differences Between Iron and Steel |
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Authors: | David J Young Huaying Yin |
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Affiliation: | 1. School of Materials Science & Engineering, University of New South Wales, Sydney, NSW, 2052, Australia
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Abstract: | High purity iron and a low carbon, low silicon steel were oxidised at temperatures of 800–1,200 °C, in atmospheres of N2–H2–H2O and N2–O2–H2O. Scales of wüstite grew at low oxygen potentials, and of FeO/Fe3O4/Fe2O3 at high oxygen potentials, both according to parabolic kinetics after an initial transient period. The iron and steel behaved similarly in the O2/H2O gases, but not in H2/H2O, where the steel oxidised much more slowly than the iron. The rate for steel increased with $ p_{{H_{2} O}} $ at fixed $ p_{{O_{2} }} , $ but for iron was almost independent of $ p_{{H_{2} O}} , $ whilst rates for both metals increased with $ p_{{O_{2} }} $ at fixed $ p_{{H_{2} O}} $ . These results are discussed using point defect models involving hydroxyl anions and cation vacancies. Scaling rates in O2/H2O also increased with $ p_{{H_{2} O}} , $ a result attributed to gas phase transport within oxide pores which were present in the scales, but absent in wüstite grown in H2/H2O. |
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