Synthesis of highly ordered and hydrothermally stable mesoporous materials using sodium silicate as a precursor |
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Authors: | Dahai Pan Kun Qian Yu Fan Xiaojun Bao |
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Affiliation: | a State Key Laboratory of Heavy Oil Processing, China University of Petroleum, 18 Fuxue Road, Changping, Beijing 102249, PR China b Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, 220 Handan Road, Shanghai 200433, PR China |
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Abstract: | Highly ordered mesoporous silica and aluminosilicate materials with extremely high hydrothermal stability have been synthesized successfully at a high hydrothermal treatment temperature of 200 °C by using inexpensive sodium silicate and sodium aluminate as the silica source and alumina source, respectively. The resultant mesoporous materials possess a hexagonal mesostructure and extraordinary stability towards the steam treatment at 800 °C for 2 h. In addition, the direct incorporation of Al into the mesoporous framework can further enhance the hydrothermal stability of ordered mesoporous materials. Our contribution provides a commercially important approach to synthesize ordered mesoporous materials with highly hydrothermal stability, which may find potential applications for the catalytic cracking in the petroleum industry. |
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Keywords: | Mesoporous materials Hydrothermal stability Sodium silicate Block copolymer |
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