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Preparation and characterization of sol-gel derived Er-Yb codoped SiO2/TiO2 core-shell nanoparticles
Authors:Shujie Pang  Zuosen Shi  Zhanchen Cui
Affiliation:a Key Lab of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China
b Chemistry and Chemical Engineer Department, DaQing Normal University, Central Street, Ranghulu District, Daqing 163712, People's Republic of China
Abstract:
The Er3+-Yb3+ codoped silica/titania core-shell nanoparticles were prepared by hydrolysis of titanium alkoxide precursors in the presence of lanthanide ions via sol-gel method. The structure of the particles was characterized by field emission scanning electron microscopy and transmission electron microscopy. The diameter of the silica core is about 50 nm. The thickness of the titania shell is about 4 nm. A typical doping density of Er3+ in the titania shell is 4.51 at.%, and the one of Yb3+ is 12.20 at.%. The UV-vis-NIR absorption spectra and the photoluminescence spectra were also investigated.
Keywords:Nanomaterials   Luminescence   Sol-gel preparation   Optical materials and properties
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