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液相自组装制备钛酸铋功能陶瓷薄膜的工艺研究
引用本文:夏傲,黄剑锋,谈国强,刘丹. 液相自组装制备钛酸铋功能陶瓷薄膜的工艺研究[J]. 材料工程, 2011, 0(9): 14-19
作者姓名:夏傲  黄剑锋  谈国强  刘丹
作者单位:陕西科技大学教育部轻化工助剂化学与技术重点实验室,西安,710021
基金项目:国家青年科学基金项目(51002092); 陕西省自然科学基金项目(2010JM6013); 陕西科技大学自选项目(zx08-11)
摘    要:
以硝酸铋和氟钛酸铵为原料,以三氯十八烷基硅烷(OTS)为模板,利用自组装单层膜(SAM)技术,在玻璃基片上制备钛酸铋薄膜.改性基板的亲水性测定与原子力显微镜(AFM)测试表明,紫外光照射使基板由疏水转变为亲水,能够对OTS-SAM起到修饰作用.借助XRD,SEM测试手段分析了前驱液的pH值、沉积条件和煅烧温度对Bi4 ...

关 键 词:自组装单层膜  钛酸铋  薄膜  工艺

Fabrication of Bi_4Ti_3O_(12) Functional Ceramic Film by Self-assembled Monolayers Technique
XIA Ao,HUANG Jian-feng,TAN Guo-qiang,LIU Dan. Fabrication of Bi_4Ti_3O_(12) Functional Ceramic Film by Self-assembled Monolayers Technique[J]. Journal of Materials Engineering, 2011, 0(9): 14-19
Authors:XIA Ao  HUANG Jian-feng  TAN Guo-qiang  LIU Dan
Affiliation:XIA Ao,HUANG Jian-feng,TAN Guo-qiang,LIU Dan(Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry(Ministry of Education),Shaanxi University of Science and Technology,Xi'an 710021,China)
Abstract:
Bi4Ti3O12 film was prepared on the glass substrate by the self-assembled monolayer(SAM) technique with Bi(NO3)3 and(NH4)2TiF6 as the raw material and octadecyltrichlorosilane(OTS) as the template.Hydrophilic characteristic measure of glass wafers and photographs of atomic force microscopy(AFM) indicate that the hydrophobe substrate changes into hydrophile by UV irradiation,and a modification of OTS-SAM is realized by UV light.Effects of pH values,deposition conditions and calcining temperatures on the phase...
Keywords:self-assembled monolayer  Bi4Ti3O12  thin film  fabrication  
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