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| 锌锰干电池两种代汞缓蚀剂 | |
| 引用本文： | 黄楚宝,熊岳平,多晶琪,周定. 锌锰干电池两种代汞缓蚀剂[J]. 电池, 1994, 0(6) |
| 作者姓名： | 黄楚宝 熊岳平 多晶琪 周定 |
| 作者单位： | 吉林大学，哈尔滨工业大学 吉林 130023，黑龙江 150005 |
| 摘 要： | 通过浸泡实验,极化测量考察了在26％NH_4Cl溶液中BiCl_3、有机复合物MA对锌的缓蚀性能,并与HgCl_2的情况进行了对比。结果表明铋类似于汞同为阴极型缓蚀剂,但其适用的浓度范围较窄,在有氧存在时失去缓蚀作用。MA则为阳极型缓蚀剂,有较宽的浓度适用范围,在有氧存在的条件下,仍表现较好的缓蚀作用。 |
| 关 键 词： | 代汞缓蚀剂 锌锰干电池 锌腐蚀 三氯化铋 氯化汞 |
Mercury-Substituting Inhibitors for Zinc Manganese Dry Cells |
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| Jilin University,Jilin Harbin Institute of Technology,Helongjiang Huang Chubao Xiong Yueping Duo Jingqi Zhou Ding. Mercury-Substituting Inhibitors for Zinc Manganese Dry Cells[J]. Battery Bimonthly, 1994, 0(6) | |
| Authors: | Jilin University Jilin Harbin Institute of Technology Helongjiang Huang Chubao Xiong Yueping Duo Jingqi Zhou Ding |
| Affiliation: | Jilin University,Jilin 130023Harbin Institute of Technology,Helongjiang 150006 Huang Chubao Xiong Yueping Duo Jingqi Zhou Ding |
| Abstract: | By means of immersion test and polarization measurement ,the inhibiting effect of hCl5 and organic composite MA on zinc corrosion in 26 % NH4C1 solution was investigated and companed with that of HgCl2. Analysis of experimental results showed that similar to mercury .bismuth was a cathodic type inhibitor but its applicable concentration range was narrow. On the other hand MA was an anodic type inhibitor with wider applicable concentration range. In presence of oxygen,bismuth becane invalid while MA remained effective. |
| Keywords: | Mercury-Substituting Inhibitor Zinc-Manganese Dry Cell Zinc Corro ion Bismuth Trichloride Mercury Chloride |
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