含有金属黏结相的热喷涂WC涂层在盐雾中的腐蚀行为

研究黏结相化学成分对涂层材料的耐盐雾腐蚀性能的影响，对采用超音速火焰喷涂制得的WC?17Co和WC?10Co?4Cr涂层进行电化学试验和长时间的盐雾腐蚀实验(浓度为5%的NaCl溶液，温度35°C)。结果表明：WC?10Co?4Cr涂层的耐盐雾腐蚀性能优于WC?17Co涂层。对于WC?17Co涂层，主要腐蚀行为除了粘结金属的腐蚀外还包括WC颗粒与粘结相金属之间发生的微点偶腐蚀；对于WC?10Co?4Cr涂层，形成的氧化物有利于抑制金属相与粘结相的腐蚀。说明金属材料成分是影响超音速火焰喷涂WC基涂层耐盐雾腐蚀性能的重要因素之一。

Corrosion behavior of thermal sprayed WC cermet coatings containing metallic binders in saline environment

A series of electrochemical and long-term corrosion tests were carried out in a neutral saline （5%NaCl） vapor of 35 °C on thermal sprayed WC cermet coatings containing different kinds of metallic binders in order to examine the effect of composition of binder materials on the corrosion behavior. The experimental results revealed that the overall corrosion resistance of WC-Co coating was inferior to that of WC-Co-Cr coating. For the coatings without Cr, WC-Co, general corrosion occurred in binder materials in addition to galvanic corrosion between WC particles and metallic binders in the neutral environment. By contrast, the formation of passive film in the form of surface oxide in the coatings containing Cr, WC-Co-Cr, suppressed the binder and metallic binders to be eroded. It is found that the chemical composition of metallic binder materials is one of the important factors influencing the corrosion resistance of HVOF sprayed WC cermet coatings in the neutral vapor.