The unique flow of polypropylene at the weld line behind an obstacle in injection molding |
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| Authors: | Yutaka Kobayashi Gensei Teramoto Toshitaka Kanai |
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| Affiliation: | 1. Research and Development Division, Prime Polymer Company Limited, 580‐30 Nagaura, Sodegaura, Chiba 299‐0265, Japan;2. Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma‐Machi, Kanazawa, Ishikawa 920‐1192, Japan;3. Research and Development Laboratory, Idemitsu Kosan Company Limited, Anasaki‐Kaigan, Ichihara, Chiba 299‐0193, Japan |
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| Abstract: | In this article, a weld line placed behind an obstacle in an injection‐molded plaque made of metallic mold‐in‐color polypropylene (PP) was investigated. A broad uneven glossy section was visually observed along the weld line after the v‐notch weld disappeared. Although disk‐shaped metallic pigments were oriented parallel to the wall according to laminar flow, the pigment particles at the weld behind the obstacle were ordered vertically at the center of the depth direction. In PP molded without pigment, a black line was observed at the same position in the metallic weld. Based on a measurement of the crystal structure, the black line was caused by the rapid cooling of molten PP. Elongational flow occurred along the weld line after the diminishing v‐notch weld. The unique flow ordered the pigments obliquely at the advancing flow front and disturbed the subsequent flow of hot PP which transferred heat to the crystallizing mass. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers |
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