| 丙烯酸甲酯与酚醛树脂接枝共聚反应的研究 |
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| 引用本文： | 刘盈海,白利斌,杨柏,邓奎林.丙烯酸甲酯与酚醛树脂接枝共聚反应的研究[J].热固性树脂,2004,19(5):7-10. |
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| 作者姓名： | 刘盈海 白利斌 杨柏 邓奎林 |
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| 作者单位： | 1. 河北大学化学与环境科学学院,河北,保定,071002
2. 中国科学院北京化学所,北京,100080 |
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| 基金项目： | 河北省自然科学基金资助项目(200071) |
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| 摘 要： | 在碱性水溶液体系中,以超高价态过渡金属二过碘酸合铜(Ⅲ)钾为氧化剂,碱性酚醛树脂(PF)的羟甲基为还原剂,通过氧化还原反应产生自由基引发丙烯酸甲酯(MA)与酚醛树脂发生接枝共聚合反应。对反应的各种因素(温度、时间、引发剂、单体浓度)对转化率、接枝参数的影响进行了研究。通过红外光谱、X射线衍射、热重、电子扫描电镜对接枝共聚物的性能进行了表征,并在此基础上探讨了反应的机理。
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| 关 键 词： | 二过碘酸合铜(Ⅲ)钾 酚醛树脂 丙烯酸甲酯 氧化还原引发剂 接枝共聚合 |
| 文章编号： | 1002-7432(2004)05-0007-04 |
GRAFT COPOLYMERIZATION OF PHENOLIC RESIN AND METHYL ACRYLATE |
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| LIU Ying-hai,BAI Li-bin,YANG Bai,DENG Kui-lin.GRAFT COPOLYMERIZATION OF PHENOLIC RESIN AND METHYL ACRYLATE[J].Thermosetting Resin,2004,19(5):7-10. |
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| Authors: | LIU Ying-hai BAI Li-bin YANG Bai DENG Kui-lin |
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| Affiliation: | LIU Ying-hai~1,BAI Li-bin~1,YANG Bai~1,DENG Kui-lin~2 |
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| Abstract: | Graft copolymers of methyl acrylate(MA) and phenolic resin (PF) had been obtained using a novel redox system-potassium diperiodatocuprate(Ⅲ) DPC/PF system in alkaline aqueous medium.Effects of different conditions(concentration of reactants and DPC temperature,reaction time) on the total conversion,percentage of grafting and efficency of grafting were examined.A tentative mechanism,single-electron-transfer process of DPC was proposed to explain the generation of radicals and the initiation of grafting.Some basic properties of the graft copolymers were also studied by X-ray diffraction,thermogravimetry and scanning electron microscope. |
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| Keywords: | diperiodatocuprate(Ⅲ) methyl acrylate phenolic resin redox initiation graft copolymerization |
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