| 微波辐射条件下H2O2氧化蒽合成蒽醌的研究 |
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| 引用本文： | 寇佳慧,郁桂云,孙林兵,王桃霞,陈虹,宗志敏,魏贤勇,李哲伟.微波辐射条件下H2O2氧化蒽合成蒽醌的研究[J].化学试剂,2005,27(6):369-371. |
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| 作者姓名： | 寇佳慧 郁桂云 孙林兵 王桃霞 陈虹 宗志敏 魏贤勇 李哲伟 |
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| 作者单位： | 1. 中国矿业大学,化学工程学院,江苏,徐州,221008
2. 韩国化学研究院,化学技术部,韩国,大田,305-600 |
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| 基金项目： | 韩国科学技术财团Brain-Pool项目资助. |
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| 摘 要： | 研究了微波辐射条件下H2O2氧化蒽的反应，考察了时间、H2O2用量、催化剂和溶剂对葸醌收率的影响。结果表明．CH3COOH浓度对蒽醌的收率影响很大，以适量的(CH3COO)3Fe作为催化剂可以增加蒽醌的收率和缩短反应时间。
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| 关 键 词： | 微波辐射 H2O2 氧化 蒽 蒽醌 |
| 文章编号： | 0258-3283(2005)06-0369-03 |
Synthesis of anthraquinone by oxidation with H2O2 under microwave irradiation |
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| KOU Jia-hui,YU Gui-yun,SUN Lin-bing,WANG Tao-xia,CHEN Hong,ZONG Zhi-min,WEI Xian-yong,Lee Chul Wee.Synthesis of anthraquinone by oxidation with H2O2 under microwave irradiation[J].Chemical Reagents,2005,27(6):369-371. |
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| Authors: | KOU Jia-hui YU Gui-yun SUN Lin-bing WANG Tao-xia CHEN Hong ZONG Zhi-min WEI Xian-yong Lee Chul Wee |
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| Affiliation: | KOU Jia-hui *1,YU Gui-yun 1,SUN Lin-bing 1,WANG Tao-xia 1,CHEN Hong 1,ZONG Zhi-min 1,WEI Xian-yong 1,Lee Chul Wee 2 |
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| Abstract: | The oxidation of anthracene with H_2O_2 under microwave irradiation was investigated.The effects of reaction time,H_2O_2 feed,catalyst and solvent were examined.The results showed that anthraquinone yield was significantly affected by the concentration of acetic acid and that using proper amount of (CH_3COO)_3Fe as catalyst could increase the anthraquinone yield and shorten the reaction time. |
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| Keywords: | microwave irradiation H_2O_2 oxidation anthracene anthraquinone |
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