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Correlation of Morphology and Viscoelastic Properties of Partially Biodegradable Polymer Blends Based on Polyamide 6 and Polylactide Copolyester
Authors:Pavel Kucharczyk  Onon Otgonzu  Takeshi Kitano  Adriana Gregorova  Darij Kreuh  Uros Cvelbar
Affiliation:1. Centre of Polymer Systems, Polymer Centre, Tomas Bata University in Zlin , Czech Republic;2. Institute for Chemistry and Technology of Materials, Graz University of Technology , Graz , Austria;3. Ekliptik , Ljubljana , Slovenia;4. Jozef Stefan Institute , Ljubljana , Slovenia
Abstract:The morphology and viscoelastic properties of newly prepared partially biodegradable polymeric blend based on polyamide 6 and commercially available co-polyester of polylactide, BioFlex®, were studied in this work. Observations by scanning electron microscopy and solvent extraction method, and rheological measurements were carried out for structural studies. Experimental data were compared with several semi-empirical models for determination of phase inversion concentration. The correlation between experimental data and models reveals the significant contribution of elasticity effect to interfacial adhesion between polyamide 6 and BioFlex, which seems to have influence on the phase inversion composition of the blends and co-continuous morphology formation.
Keywords:Bioflex  Polyamide  Polylactide co-polyester  Polymer blend  Rheological properties
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