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Acidity and Catalytic Behaviors of Ordered Mesoporous Aluminosilicate Materials Containing Zeolite Building Units
Authors:Ayyamperumal Sakthivel  Wen-Hua Chen  Shou-Heng Liu  Shing-Jong Huang  An-Ya Lo  Ying-Hou Hsu  Shawn D. Lin  Shang-Bin Liu
Affiliation:(1) Institute of Atomic and Molecular Sciences, Academia Sinica, P.O. Box 23-166, Taipei, 106, Taiwan, R.O.C;(2) Department of Chemical Engineering, Yuan Ze University, Chungli, 320, Taiwan, R.O.C;(3) Anorganisch-Chemisches, Fritz-Haber-Institut-MPG, Faradayweg 4-6, D-14195 Berlin, Germany
Abstract:
The structural and acidic properties of two new highly stable meso-/microporous composite materials (MMS-H and RMM-1) developed recently were characterized by various analytical and spectroscopic techniques. Comparing to their structural analogue, Al-MCM-48, these novel aluminosilicates materials comprising zeolite secondary building units were found to have superior catalytic activities, as illustrated by ethylbenzene alkylation reaction.
Keywords:mesoporous aluninosilicate material  zeolite building units  characterization  acidity  stability  ethylbenzene alkylation
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