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| 有机硅改性环氧树脂的制备及性能 | |
| 引用本文： | 汪明球,闫军,崔海萍,杜仕国. 有机硅改性环氧树脂的制备及性能[J]. 塑料, 2011, 40(4) |
| 作者姓名： | 汪明球 闫军 崔海萍 杜仕国 |
| 作者单位： | 1. 军械工程学院三系,河北石家庄,050003 2. 军械工程学院基础部,河北石家庄,050003 |
| 基金项目： | 国家自然科学基金(50572122); 军械工程学院基础部科研基金(JCB1006) |
| 摘 要： | 以自制的乙酰丙酮钛为催化剂,有机硅树脂TSR144为改性剂,通过化学改性的方法制备了一系列有机硅改性环氧树脂.探讨了有机硅加入量对改性环氧树脂固化物结构及性能的影响,采用IR、TGA/DTG技术对改性环氧树脂进行了表征及分析,并利用扫描电镜( SEM)观察断面的微观形貌.结果表明:随着有机硅含量增加,样品最大分解速率时的温度(T1max)呈S型曲线变化趋势；当有机硅的含量为16.7％时,复合体系的力学性能显著改善,其拉伸强度、断裂伸长率分别达到54.86 MPa,9.43％,比未改性的纯环氧树脂分别提高了8.54 MPa,2.71％. |
| 关 键 词： | 环氧树脂 有机硅 改性 乙酰丙酮钛 功能材料 微观形貌 |
Preparation and Properties of Silicone Modified Epoxy Resins |
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| WANG Ming-qiu,YAN Jun,CUI Hai-ping,DU Shi-guo. Preparation and Properties of Silicone Modified Epoxy Resins[J]. Plastics, 2011, 40(4) | |
| Authors: | WANG Ming-qiu YAN Jun CUI Hai-ping DU Shi-guo |
| Affiliation: | WANG Ming-qiu1,YAN Jun1,CUI Hai-ping2,DU Shi-guo1(1.The 3rd Department of Ordnance Engineering College,Shijiazhuang,Hebei 050003,China,2.Physics and Chemistry Section of Ordnance Engineering College,China) |
| Abstract: | A series of silicone modified epoxy resins were successfully prepared by chemical-modification methods using TSR144 via titanium acetylacetonate as catalyst.The influences of contents of organic silicone on the structure and properties of cured materials were investigated by using IR,TGA/DTG techniques,and then microstructure of the cured materials were observed via scanning electron microscopic(SEM).The results showed that the temperatures at the maximum weight loss rate presented the characteristics of a ... |
| Keywords: | epoxy resin silicone modification titanium acetylacetonate functional materials micro-structure |
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