| 柴油超深度加氢脱硫机理及氮化物影响的研究进展 |
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| 引用本文： | 白天忠,刘继华,柳伟,宋永一,孙厚祥,包洪洲.柴油超深度加氢脱硫机理及氮化物影响的研究进展[J].炼油技术与工程,2011,41(8):1-4. |
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| 作者姓名： | 白天忠 刘继华 柳伟 宋永一 孙厚祥 包洪洲 |
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| 作者单位： | 1. 辽宁石油化工大学,辽宁省抚顺市,113001
2. 中国石油化工股份有限公司抚顺石油化工研究院,辽宁省抚顺市,113001 |
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| 摘 要： | 介绍了柴油超深度加氢脱硫（HDS）机理及氮化物对其的影响。介绍了硫化物存在形式、相对反应速率及其HDS反应路径。结果表明：非噻吩类硫化物HDS活性较高,在加氢催化剂活性中心上直接氢解生成相应的烃和H2S;催化剂的酸性在加氢精制工艺中对裂化反应有促进作用,必须考虑到脱硫率和催化剂寿命的最优化选择;碱性氮化物比非碱性氮化物对HDS的抑制作用强,不同催化剂的抗氮化物毒化能力不同,氮化物对HDS的两种路径影响不同,对加氢（HYD）路径的抑制作用强于直接氢解（DDS）路径;柴油馏分超深度HDS机理及氮化物对其抑制机理的研究,可以指导高活性、抗抑制剂催化剂的开发,从而缓和工艺条件,延长催化剂寿命。
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| 关 键 词： | 机理 超深度脱硫 柴油 氮化物 |
Study on mechanism of diesel ultra-deep hydrodesulfurization and impact of nitrogen compounds |
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| Bai Tianzhong,Liu Jihua,Liu Wei,Song Yongyi,Sun Houxiang,Bao Hongzhou.Study on mechanism of diesel ultra-deep hydrodesulfurization and impact of nitrogen compounds[J].Petroleum Refinery Engineering,2011,41(8):1-4. |
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| Authors: | Bai Tianzhong Liu Jihua Liu Wei Song Yongyi Sun Houxiang Bao Hongzhou |
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| Affiliation: | Bai Tianzhong1,Liu Jihua2,Liu Wei2,Song Yongyi2,Sun Houxiang1,Bao Hongzhou1(1.Liaoning Shihua University,Fushun,Liaoning 113001,2.SINOPEC Fushun Research Institute of Petroleum and Petrochemicals,Liaoning 113001) |
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| Abstract: | The mechanisms of diesel ultra-deep desulfurization and impact of nitrogen compounds are introduced.The forms of nitrogen compounds,the relative reaction rate and HDS reaction route are specifically studied.The results show that the non-thiophene sulfides have a higher HDS activity,which can directly be hydrogenolyzed into hydrocarbons and H2S on the active site of hydrogenation catalysts.As the acid site of catalyst has a promoting effect on cracking reaction in hydrogenation process,the desulfurization ra... |
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| Keywords: | mechanism ultra-deep desulfurization diesel nitrogen compounds |
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