| 原子转移自由基乳液聚合研究进展 |
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| 引用本文： | 张立,张教强,史长明,易娜,白晓慧. 原子转移自由基乳液聚合研究进展[J]. 中国胶粘剂, 2013, 0(5): 44-49 |
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| 作者姓名： | 张立 张教强 史长明 易娜 白晓慧 |
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| 作者单位： | 西北工业大学理学院 |
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| 摘 要： | 原子转移自由基聚合(ATRP)作为一种可控/活性聚合方法,可对聚合物结构进行精确控制;乳液聚合以水作为分散介质,具有经济、环保等特点。因此,乳液ATRP结合了两者的优点,具有工业化生产的潜力。首先分析了影响乳液ATRP的各种因素,然后综述了正向ATRP、RATRP(反向ATRP)、SR&NI ATRP(正向/反向同时进行的ATRP)和AGET ATRP(电子转移活化剂ATRP)等机制及研究进展,最后对乳液ATRP的发展方向进行了展望。
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| 关 键 词： | 原子转移自由基聚合 乳液 活性自由基聚合 |
Research progress of atom transfer radical polymerization in emulsion |
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| Zhang Li,Zhang Jiaoqiang,Shi Changming,Yi Na,Bai Xiaohui. Research progress of atom transfer radical polymerization in emulsion[J]. China Adhesives, 2013, 0(5): 44-49 |
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| Authors: | Zhang Li Zhang Jiaoqiang Shi Changming Yi Na Bai Xiaohui |
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| Affiliation: | (College of Science,Northwestern Polytechnical University,Xi’an 710072,China) |
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| Abstract: | The atom transfer radical polymerization(ATRP) as a kind of controlled/living polymerization method,can accurately control structure of polymer.The emulsion polymerization with water as dispersion medium,has economy and environment-friendly characteristics.The emulsion-ATRP with both advantages,had a industrialized production potential.First,various influences factors of emulsion-ATRP were analyzed.Then,the mechanisms and research progresses of positive ATRP,RATRP(reverse ATRP),SR&NI ATRP(positive/reverse ATRP) and AGET ATRP(electron transfer activating agent ATRP) were summarized.Finally,the development directions of emulsion-ATRP were expected. |
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| Keywords: | atom transfer radical polymerization(ATRP) emulsion living radical polymerization |
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