Thermodynamic calculation of phase equilibria of the Bi-Sn-Zn system |
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| Authors: | Dmitri V. Malakhov Xing Jun Liu Ikuo Ohnuma Kiyohito Ishida |
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| Affiliation: | (1) Department of Materials Science and Engineering, McMaster University, L8S 4M1 Hamilton, ON, Canada;(2) Department of Materials Science, Graduate School of Engineering, Tohoku University, 980-8579 Sendai, Japan |
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| Abstract: | A thermodynamic assessment of the Bi-Sn-Zn ternary system was carried out by considering the experimental data including the phase equilibria and thermodynamic properties on the basis of the CALPHAD method. A set of optimized thermodynamic parameters has been obtained, which leads to a very good fit between calculation and experiments. In particular, the thermodynamic calculations in the Sn-rich portion are presented in view of the recent progress in Pb-free solder alloys. |
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