| Synthesis, Characterization and Fluorescence of Phenylcarboxymethyl Sulfoxide Complexes with Lanthanide Nitrates |
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| 作者姓名： | 李文先 张东凤 |
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| 作者单位： | College of Chemistry and Chemical Industry，Inner Mongolia University，Hohhot 010021，China |
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| 基金项目： | ProjectsupportedbytheNaturalScientificFoundationofInnerMongolia ( 2 0 0 0 1 3 0 1 ) |
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| 摘 要： | Ｒａｒｅｅａｒｔｈｃｏｍｐｌｅｘｅｓｗｉｔｈｓｕｌｆｏｘｉｄｅａｎｄａｒｏｍａｔｉｃｃａｒｂｏｘｙｌａｃｉｄｈａｖｅｂｅｅｎｗｉｄｅｌｙｓｔｕｄ ｉｅｄ1～ 3 ] .Ｉｔｉｓｐｒｏｖｅｄｔｈａｔｔｈｅｙｂｏｔｈｈａｖｅｂｅｔ ｔｅｒｆｌｕｏｒｅｓｃｅｎｃｅｃｈａｒａｃｔｅｒ .Ｈｏｗｅｖｅｒｔｈｅａｒｏ ｍａｔｉｃｃａｒｂｏｘｙｌｏｆｒａｒｅｅａｒｔｈｃｏｍｐｌｅｘｅｓｈａｖｅｖｅｒｙｈｉｇｈｆｌｕｏｒｅｓｃｅｎｃｅｅｍｉｓｓｉｏｎｉｎｔｅｎｓｉｔｙａｎｄｓｔａｂｉｌｉｔｙ ,ｂｕｔｓｏｌｕｂｉｌｉｔｙｉ…
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| 关 键 词： | 硝酸盐 稀土 苯基羧甲基亚砜 合成 表征 荧光性能 镧系元素 |
Synthesis, Characterization and Fluorescence of Phenylcarboxymethyl Sulfoxide Complexes with Lanthanide Nitrates |
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| Li Wenxian,Zhang Dongfeng.Synthesis, Characterization and Fluorescence of Phenylcarboxymethyl Sulfoxide Complexes with Lanthanide Nitrates[J].Journal of Rare Earths,2002,20(5):430-433. |
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| Authors: | Li Wenxian Zhang Dongfeng |
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| Abstract: | Phenylcarboxymethyl Sulfoxide, PhSOCH2COOH(LH), complexes of six lanthanide nitrates: Ln2L2(NO3)4*2LH*nH2O(where Ln=La, Ce, Pr, Nd, Sm, Eu) were synthesized. Elemental analyses, molar conductivities, IR, 1HNMR and TG-DTA measurements were used to characterize the complexes. The results show that the ligand(L) is coordinated to metal ions through two oxygen atoms of the carboxyl group and one oxygen atom of the sulfoxide moieties. Neutral ligang (LH)is coordinated to two metal ions through two oxygen atoms of carboxyl group as an asymmetrical bridging bidentate. The fluorescence spectra of Eu3+ complex indicates that there is no inversion symmetry at the site of Eu3+ ion, but the emission intensity of fluorescence is quite good.The solubility of the complexes is very good in water. |
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| Keywords: | rare earths phenylcarboxymethyl sulfoxide fluorescence spectrum |
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