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焦炉煤气直接氧化制合成气工艺条件优化
引用本文:赵辉,陈倩倩,陈宏刚,张永发.焦炉煤气直接氧化制合成气工艺条件优化[J].煤炭转化,2009,32(3).
作者姓名:赵辉  陈倩倩  陈宏刚  张永发
作者单位:1. 中国石油大学重质油国家重点实验室,257061,山东东营
2. 太原理工大学煤科学与技术教育部和山西省重点实验室,030024,太原
基金项目:国家重点基础研究发展规划(973计划),山东省优秀中青年科学家科研奖励基金 
摘    要:为进一步优化焦炉煤气非预混燃烧直接制备合成气的工艺参数,对焦炉煤气在贫氧条件下发生非预混燃烧的过程进行数值模拟研究,得到了反应器内温度及产物组成分布的详细分布状况.模拟结果表明,反应在靠近氧气入口的区域内发生.从数值模拟的结果来看,反应器壁温对反应结果有非常重要的影响:提高反应器壁温有利于提高合成气的选择性,但是煤气中甲烷的转化率有所降低.因此,反应器壁温是能够控制本工艺总体反应效果的重要参数,工艺优化过程中应该特别注意.

关 键 词:非预混燃烧  部分氧化  合成气

NUMERICAL SIMULATION AND OPTIMIZATION OF SYNGAS PRODUCTION BY PARTIAL OXIDATION OF COKE OVEN GAS IN NON-PREMIXED CONDITION
Zhao Hui,Chen Qianqian,Chen Honggang,Zhang Yongfa.NUMERICAL SIMULATION AND OPTIMIZATION OF SYNGAS PRODUCTION BY PARTIAL OXIDATION OF COKE OVEN GAS IN NON-PREMIXED CONDITION[J].Coal Conversion,2009,32(3).
Authors:Zhao Hui  Chen Qianqian  Chen Honggang  Zhang Yongfa
Affiliation:State Key Laboratory of Heavy Oil Processing China University of Petroleum;257061 Dongying;Shandong;Key Laboratory of Coal Science and Technology of Shanxi Province and Ministry of Education;Taiyuan University of Technology;030024 Taiyuan
Abstract:Non-premixed combustion of coke oven gas under low oxygen condition was investigated through computational fluid dynamic(CFD)simulation coupled with radiation heat transfer.Temperature profile and product distribution in reactor were obtained from simulation.Calculated temperature profile indicates that oxygen react strongly with coke oven gas in region near the oxygen nozzle and the temperature in this region increase sharply.Noticeable influence of reactor wall temperature on product distribution could be...
Keywords:non-premixed combustion  partial oxidation  syngas  
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