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巯基泥炭吸附重金属离子机理研究
引用本文:周建伟.巯基泥炭吸附重金属离子机理研究[J].化学世界,2002,43(2):59-61.
作者姓名:周建伟
作者单位:平原大学化工系,河南新乡,453003
基金项目:河南省科技攻关项目资助课题 ( 991190 10 8)
摘    要:从热力学、动力学及 XPS三个方面探讨了巯基泥炭对重金属离子的吸附机理。结果表明 :吸附过程以化学吸附为主。外表面、内表面对 Zn2 + 的吸附率分别为 1 6% ,84% ;Cu2 + 为 1 7% ,83% ;Pb2 +为 5 % ,95 % ;且吸附 Cd2 +完全由内扩散所控制

关 键 词:巯基泥炭  重金属离子  吸附机理
文章编号:0367-6358(2002)02-0059-03

Study on Adsorption Mechanism of Metal Ionson Sulfhydryl-peat
ZHOU Jian,wei.Study on Adsorption Mechanism of Metal Ionson Sulfhydryl-peat[J].Chemical World,2002,43(2):59-61.
Authors:ZHOU Jian  wei
Abstract:The adsorption mechanism of a novel separation adsorbent containing sulfhydryl group was studied in terms of themodynamics and kinetics. The adsorbent is able to absorb heavy metal ions: Zn 2+ 、Pb 2+ 、Cd 2+ and Cu 2+ . Chemisorption is predominant. The adsorption capacities of the external and internal surface are 16% and 84% for Zn 2+ , 17% and 83% for Cu 2+ , 5% and 95% for Pb 2+ , respectively, Whereas the adsorption of Cd 2+ is fully controlled by internal diffusion.
Keywords:sulfydryl  peat  heavy metal ion  adsorption mechanism
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