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溅射TiAlCr涂层对Ti-24Al-14Nb-3V抗氧化性能的影响
引用本文:关春红 李世琼. 溅射TiAlCr涂层对Ti-24Al-14Nb-3V抗氧化性能的影响[J]. 中国有色金属学报, 1999, 9(2): 247-252
作者姓名:关春红 李世琼
作者单位:中国科学院金属腐蚀与防护研究所,金属腐蚀与防护国家重点实验室,北京钢铁研究总院
基金项目:国家“八六三”计划资助,国家杰出青年基金
摘    要:研究了溅射Ti50Al10Cr及Ti50Al20Cr涂层对Ti24Al14Nb3V抗高温氧化性能的影响。结果表明,在800℃下,Ti50Al10Cr及Ti50Al20Cr涂层表面由于可形成粘附性良好的Al2O3膜,大大改善了Ti24Al14Nb3V的抗高温氧化性能。900℃时在Ti50Al10Cr涂层表面长出大量TiO2,导致其氧化增重较大;而在Ti50Al20Cr涂层表面生成了连续Al2O3,其抗氧化性能良好。然而,由于TiAlCr涂层与基体热膨胀系数不同,在循环氧化过程中涂层出现一些裂纹,导致其抗循环氧化性能有所下降。

关 键 词:Ti-24Al-14Nb-3V  高温氧化  TiAlCr涂层

EFFECT OF SPUTTERED TiAlCr COATINGS ON OXIDATION RESISTANCE OF Ti24Al14Nb3V
Guan Chunhong,Wang Fuhui,Tang Zhaolin and Wu Weitao State Key Laboratory for Corrosion and Protection. EFFECT OF SPUTTERED TiAlCr COATINGS ON OXIDATION RESISTANCE OF Ti24Al14Nb3V[J]. The Chinese Journal of Nonferrous Metals, 1999, 9(2): 247-252
Authors:Guan Chunhong  Wang Fuhui  Tang Zhaolin  Wu Weitao State Key Laboratory for Corrosion  Protection
Affiliation:Guan Chunhong,Wang Fuhui,Tang Zhaolin and Wu Weitao State Key Laboratory for Corrosion and Protection,Institute of Corrosion and Protection of Metals,The Chinese Academy of Sciences,Shenyang 110015,P. R. China Li Shiqiong Central Iron and Ste
Abstract:The effect of sputtered Ti50Al10Cr and Ti50Al20Cr coatings on oxidation resistance of Ti24Al14Nb3V in static air at 800900 was studied .The uncoated TiAl alloys showed poor resistance due to the formation of porous mixed Al2O3 TiO2 AlNbO4 scale. The Ti50Al10Cr and Ti50Al20Cr coatings could remarkably improve the oxidation resistance of Ti24Al14Nb3V due to the formation of protective Al2O3 layer. A great deal of TiO2 appeared on the Ti50Al10Cr coating , which led to great mass gain at high temperatures. Both coatings cracked during cyclic oxidation due to the difference of thermal expansion coefficients between the TiAlCr coatings and the substrate.
Keywords:Ti24Al14Nb3Vhigh temperature oxidationTiAlCr coatings
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